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CAS 112022-81-8: (3aS)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole

Formula:C18H20BNO
InChI:InChI=1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1
InChI key:InChIKey=VMKAFJQFKBASMU-KRWDZBQOSA-N
SMILES:CB1OC([C@]2(N1CCC2)[H])(C3=CC=CC=C3)C4=CC=CC=C4
Synonyms:
  • (3AS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
  • (3aS)-1-methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
  • (3aS)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
  • (S)-(-)-2-Methyl-CBS-oxazaborolindine
  • (S)-2-Methyl-CBS-oxazaborolidine
  • (S)-3,3-Diphenyl-1-Methyltetrahydro-1H,3H-Pyrrolo[1,2-c][1,3,2]Oxazaborole
  • (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
  • (S)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
  • (S)-CBS reagent
  • (S)-Me-CBS
  • (S)-Methyl-CBS
  • See more synonyms
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Found 11 products.
  • (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene, AcroSeal™

    Controlled Product
    CAS:
    This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
    Formula:C18H20BNO
    Color and Shape:Liquid, Colorless to amber
    Molecular weight:277.17

    Ref: AC-43603

    50ml
    Discontinued
    Discontinued product
  • (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine - 1.0M in toluene

    CAS:
    (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine - 1.0M in toluene is an organic chemical that has been used as a reagent for the synthesis of luliconazole and other compounds. It is typically prepared by liquid phase Friedel Crafts acylation with (S)-1-(chloromethyl)benzene in the presence of hydrochloric acid or by cyanosilylation of (S)-phenylacetonitrile. The reduction products are generated from the reaction solution and can be used as a substrate molecule for the preparation of other compounds.
    Formula:C18H20BNO
    Purity:Min. 95%
    Color and Shape:Clear Liquid
    Molecular weight:277.17 g/mol

    Ref: 3D-FD31596

    1g
    Discontinued
    2g
    Discontinued
    5g
    Discontinued
    10g
    Discontinued
    25g
    Discontinued
    Discontinued product
  • (S)-2-Methyl-CBS-oxazaborolidine, 1M soln. in toluene

    CAS:
    (S)-2-Methyl-CBS-oxazaborolidine is used as an oxazaborolidine catalyst. It is also employed in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2-symmetrical ferrocenyl diols and propargyl alcohols. It is an anhydrous catalyst for CBS reduction reaction. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
    Formula:C18H20BNO
    Color and Shape:liquid, Clear to slightly hazy colourless
    Molecular weight:277.17

    Ref: 02-L14583

    5ml
    To inquire
    25ml
    To inquire
  • (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole

    CAS:
    Formula:C18H20BNO
    Purity:97%
    Color and Shape:Solid
    Molecular weight:277.1685

    Ref: IN-DA00327O

    1g
    25.00€
    5g
    30.00€
    10g
    49.00€
    15g
    57.00€
    25g
    71.00€
    100g
    153.00€
    500g
    502.00€
  • (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine

    CAS:
    Formula:C18H20BNO
    Purity:>98.0%(T)
    Color and Shape:White to Almost white powder to crystal
    Molecular weight:277.17

    Ref: 3B-D2131

    1g
    51.00€
    5g
    208.00€
  • CALLERY™ (S)-Methyl oxazaborolidine, 1M in toluene

    CAS:
    (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] (S)-CBS Catalyst
    Formula:C18H20BNO
    Color and Shape:colorless to amber liq.
    Molecular weight:277.17

    Ref: 08-05-1001

    10ml
    128.00€
    50ml
    488.00€
  • (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene

    Controlled Product
    CAS:
    This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
    Formula:C18H20BNO
    Color and Shape:Solution, Colorless to amber
    Molecular weight:277.17

    Ref: AC-36977

    25ml
    Discontinued
    Discontinued product
  • (S)-2-Methyl-CBS-oxazaborolidine

    CAS:
    (S)-2-Methyl-CBS-oxazaborolidine
    Formula:C18H20BNO
    Purity:0.97
    Color and Shape: white solid
    Molecular weight:277.17g/mol

    Ref: 54-OR906511

    5g
    32.00€
    25g
    59.00€
    100g
    186.00€
    500g
    746.00€
    2.5kg
    3,243.00€
  • (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine (ca. 1mol/L in Toluene)

    CAS:
    Formula:C18H20BNO
    Color and Shape:Colorless to Light yellow clear liquid
    Molecular weight:277.17

    Ref: 3B-D5912

    5ml
    81.00€
    25ml
    204.00€
  • (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine

    CAS:
    (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine is an interesting molecule with a variety of uses. It can be used to synthesize luliconazole in the Friedel-Crafts acylation reaction and has shown growth inhibitory activity against a wide range of bacteria. This compound has been used as a substrate molecule for reductive chlorination to obtain chloride and reduction products. In addition, (S)-5,5-diphenyl-2-methyl-3,4-propano-1,3,2 oxazaborolidine has also been used for the synthesis of cyanosilylation reactions or liquid phase cross coupling reactions.
    Formula:C18H20BNO
    Purity:Min. 95%
    Molecular weight:277.17 g/mol

    Ref: 3D-FD31740

    ne
    Discontinued
    Discontinued product
  • (S)-Methyloxazaborolidine 1M in toluene

    CAS:
    Purity:95.0%
    Color and Shape:Liquid
    Molecular weight:277.1700134277344

    Ref: 10-F043436

    100ml
    247.00€