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CAS 12112-67-3: Di-μ-chlorobis[(1,2,5,6-η)-1,5-cyclooctadiene]diiridium
Formula:C16H24Cl2Ir2
InChI:InChI=1S/2C8H12.2ClH.2Ir/c2*1-2-4-6-8-7-5-3-1;;;;/h2*1-2,7-8H,3-6H2;2*1H;;/q;;;;2*+1/p-2
InChI key:InChIKey=ZFOUDQNHNLDNLD-UHFFFAOYSA-L
SMILES:[Ir+]1234([Cl-][Ir+]567([Cl-]1)[CH]8=[CH]5CC[CH]6=[CH]7CC8)[CH]9=[CH]2CC[CH]3=[CH]4CC9
Synonyms:- (1,5-Cyclooctadiene)chloroiridium dimer
- (1,5-Cyclooctadiene)iridium chloride dimer
- (η4-1,5-Cyclooctadiene)iridium chloride dimer
- (η<sup>4</sup>-1,5-Cyclooctadiene)iridium chloride dimer
- 1,5-Cyclooctadiene, iridium complex
- 1,5-cyclooctadiene, chloride, (1Z,5Z)-, diiridium salt
- 5-Chlorobis(1,5-cyclooctadiene)diiridium
- Bis((μ-chloro)(1,5-cyclooctadiene)iridium)
- Bis(1,5-cyclooctadiene)diiridium(I) dichloride
- Bis(chloro(1,5-cyclooctadiene)iridium)
- Bis(chloro(cyclooctadiene)iridium)
- See more synonyms
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Found 11 products.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride
CAS:Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2'-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.Formula:C16H24Cl2Ir2Purity:Min. 95%Molecular weight:671.7 g/molchloro(1,5-cyclooctadiene)iridium(I) dimer
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Formula:C16H24Cl2Ir2Color and Shape:Powder, Orange to redMolecular weight:671.70Bis(1,5-cyclooctadiene)diiridium(I) Dichloride
CAS:Controlled ProductApplications Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine. References Xia, J., et al.: Chem. Eur. J., 22, 18354-18357 (2016); Padevet, J., et al.: Beilstein J. Org. Chem., 12, 1185-1195 (2016)Formula:C16H22Cl2Ir2Color and Shape:NeatMolecular weight:669.686Bis(1,5-cyclooctadiene)diiridium(I) dichloride
CAS:Bis(1,5-cyclooctadiene)diiridium(I) dichloridePurity:95+%Color and Shape:Red CrystalsMolecular weight:671.70g/molIRIDIUM(I) CYCLOOCTADIENE CHLORIDE, dimer
CAS:Formula:C16H24Cl2Ir2Color and Shape:Orange-Red SolidMolecular weight:671.71Chloro(1,5-cyclooctadiene)iridium(I) Dimer
CAS:Formula:C16H24Cl2Ir2Purity:>93.0%(T)Color and Shape:Orange to Amber to Dark red powder to crystalMolecular weight:671.70Di-µ-chloro bis[cycloocta-1,5-dienyl]iridium(I); 99.95% (metals basis)
CAS:Formula:Ir(C8H12)ClMolecular weight:671.71Bis(1,5-cyclooctadiene)diiridium(I) dichloride
CAS:Formula:C16H24Cl2Ir2Purity:98%Color and Shape:SolidMolecular weight:671.7018Chloro(1,5-cyclooctadiene)iridium(I) dimer, Ir 57.2%
CAS:Chloro(1,5-cyclooctadiene)iridium(I) dimer is widely used as a precursor to other iridium complexes, which finds application in homogeneous catalysis like carbonylation, hydrosilylation, hydrofomylation, asymmetric allylic substitutions, metathesis and chiral catalysis reactions. It is involved in the preparation of Crabtree's catalyst, which is used for hydrogenation and hydrogen-transfer reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Formula:C16H24Cl2Ir2Molecular weight:671.70Bis(1,5-cyclooctadiene)diiridium(I) dichloride
CAS:Purity:98.0%Color and Shape:Solid, Crystalline Powder or PowderMolecular weight:671.701753616333Chloro-1,5-cyclooctadiene iridium(I) dimer, 99%
CAS:Chloro-1,5-cyclooctadiene iridium(I) dimer, 99%Formula:IrCl(C8H12)Purity:99%Color and Shape:red to orange pwdr.Molecular weight:671.71
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