CAS 131211-27-3: Di-1-adamantylphosphine
Formula:C20H31P
InChI:InChI=1S/C20H31P/c1-13-2-15-3-14(1)8-19(7-13,9-15)21-20-10-16-4-17(11-20)6-18(5-16)12-20/h13-18,21H,1-12H2
InChI key:InChIKey=RRRZOLBZYZWQBZ-UHFFFAOYSA-N
SMILES:P(C12CC3CC(C1)CC(C2)C3)C45CC6CC(C4)CC(C5)C6
Synonyms:- Bis(adamant-1-yl)phosphine
- Bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphine
- Bis(tricyclo[3.3.1.1<sup>3,7</sup>]dec-1-yl)phosphine
- Diadamantylphosphine
- Phosphine, bis(tricyclo[3.3.1.1<sup>3,7</sup>]dec-1-yl)-
- Phosphine, bis(tricyclo[3.3.1.13,7]dec-1-yl)-
- Di-1-adamantylphosphine
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Di-1-adamantylphosphine, min. 97%
CAS:Di-1-adamantylphosphine, min. 97%Formula:(C10H15)2PHPurity:min. 97%Color and Shape:white pwdr.Molecular weight:302.43Phosphine, bis(tricyclo[3.3.1.13,7]dec-1-yl)-
CAS:Formula:C20H31PPurity:98%Color and Shape:SolidMolecular weight:302.4339Di-1-adamantylphosphine
CAS:Di-1-adamantylphosphine (DAP) is a coordination compound that belongs to the group of organophosphorus compounds. DAP is a catalyst in organic reactions and has been used as a homogeneous catalyst for the synthesis of aryl chlorides from aryl halides, such as benzyl chloride. DAP binds to the metal center using its two phosphines and forms an adduct with the metal center. The formation of this adduct may be due to hydrogen bonding or an intermolecular hydrogen bond. The reaction mechanism of DAP is not well understood, but it has been proposed that electron transfer occurs between the metal center and one of its ligands which results in the removal of chloride from one of them. This process produces a new ruthenium complex, which can then react with another molecule to form another ruthenium complex.Formula:C20H31PPurity:Min. 95%Molecular weight:302.44 g/molDi-1-adamantylphosphine
CAS:Formula:C20H31PPurity:>95.0%(GC)Color and Shape:White to Almost white powder to crystalMolecular weight:302.44
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