CAS 15243-33-1: triruthenium dodecacarbonyl

Ruthenium carbonyl

Triruthenium dodecacarbonyl is a group p2 metal carbonyl. It has a thermal expansion of 5.5 x 10-6 K-1 and an enthalpy of formation of -12.7 kJ mol-1. This compound undergoes reactions with amines, resulting in the formation of diazonium salts. FTIR spectroscopy has been used to identify the presence of nitrogen atoms in this molecule, which are responsible for its strong absorption bands in the region between 3200 and 3400 cm-1. The carbonyl group found in triruthenium dodecacarbonyl reacts with fatty acids to produce tiglic acid, a chemical substance that can be used as a raw material for the production of synthetic ruthenium. Picolinic acid, a natural product found in plants, also reacts with triruthenium dodecacarbonyl and copper complex to form an ion pair known

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF). This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Ruthenium carbonyl, 99%