Bis(trifluoromethyl)nitroxide is a stable organic radical characterized by the presence of two trifluoromethyl groups attached to a nitroxide moiety. Its molecular structure features a nitrogen atom bonded to an oxygen atom, which is part of a stable radical due to the resonance stabilization provided by the adjacent trifluoromethyl groups. This compound is known for its distinctive properties, including high thermal stability and solubility in various organic solvents. The trifluoromethyl groups contribute to its unique electronic properties, making it a valuable reagent in organic synthesis and materials science. Additionally, bis(trifluoromethyl)nitroxide exhibits paramagnetic behavior, which can be utilized in electron paramagnetic resonance (EPR) spectroscopy for studying molecular dynamics and interactions. Its applications extend to areas such as polymer chemistry, where it can serve as a spin label or radical initiator. Overall, bis(trifluoromethyl)nitroxide is a significant compound in both academic research and industrial applications due to its distinctive chemical characteristics.

bis(trifluoromethyl)nitroxide

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Oxo[bis(trifluoromethyl)]ammonium is a member of the oxoacids of nitrogen. It has been found to be a volatile liquid with boiling point at -80°C and vaporization enthalpy of 2.07 kJ/mol. The experimental data for this compound are given in the table below:

Column 1 Column 2 Column 3
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Experimental Data 
Experimental Value 
Parameter 
Source 
Chemical Formula 
Experimental Values

CAS 2154-71-4: bis(trifluoromethyl)nitroxide

Oxo[Bis(Trifluoromethyl)]Ammonium

Ref: 3D-FO80911