CAS 21797-13-7: Tetrakis(acetonitrile)palladium(II) tetrafluoroborate

Applications Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation. References Feldman, J., et al.: Organometallics, 16, 1514 (1997); Johnson, L., et al.: PCT Int. Appl., WO 9623010 A2 19960801 (1996); Poppenbery, J., et al.: Surface Sci., 2011; Pijnenburg, N., et al.: Dalton Transactions, 40, 8896 (2011); Kilpin, K., et al.: Inorg. Chem., 50, 6334 (2011)

Tetrakis(Acetonitrile)Palladium(II) Tetrafluoroborate

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, min. 98%

Tetrakis(acetonyl)palladium(II) tetrafluoroborate is an organometallic compound that has been used as a catalyst in organic synthesis. It is a coordination complex of palladium with the formula Pd(OAc)(BF4). The salt is soluble in non-polar solvents such as toluene and hexane, but insoluble in water. Tetrakis(acetonyl)palladium(II) tetrafluoroborate catalyzes the formation of carbon-carbon bonds by cross-coupling reactions. This type of reaction involves the use of palladium as a catalyst. The reaction mechanism is based on ligand exchange and substitution reactions and intramolecular hydrogen transfer. Tetrakis(acetonyl)palladium(II) tetrafluoroborate can be used for arylations and supramolecular chemistry.

Acts as a precursor for:Synthesis of dendritic SCS-pincer palladium complexes.Palladium complexes of click ligands.Dipalladium catalysts for use in Heck cross-coupling5, Suzuki cross-coupling, and aldehyde olefination.This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.