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CAS 261948-85-0: Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Formula:C48H38O4P2Ru
Synonyms:- Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-
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(S)-Ru(OAc)2(BINAP)
CAS:The mechanism of the Ru-catalyzed hydrogenation of 2-butynoic acid to butyric acid is a three-step process. The first step involves the addition of a proton and an electron from H2O to the substrate, forming a carbonyl compound. The second step involves the transfer of a hydride ion from Ru to the carbonyl compound, forming an alcohol. The third step involves the elimination of H2O with simultaneous formation of a double bond and release of CO2. This reaction has been shown to be catalytic in acidic conditions, recycling Ru and producing no emissions. The active catalyst is (S)-Ru(OAc)2(BINAP). The major functionalities are mesoporous silica and tiglic acid, which enhance reactivity by providing pairwise interactions between substrates and catalyst.Formula:C48H38O4P2RuPurity:Min. 95%Molecular weight:841.83 g/molRef: 3D-FR164040
Discontinued productDiacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)₂[(S)-binap]
CAS:Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-binap]Formula:C48H38O4P2RuColor and Shape:pale yellow pwdr.Molecular weight:841.83Ruthenium, bis(acetato-κO,κO')[1,1'-(1S)-[1,1'-binaphthalene]-2,2'-diylbis[1,1-diphenylphosphine-κP]]-, (OC-6-22)-
CAS:Formula:C48H38O4P2RuPurity:95%Color and Shape:SolidMolecular weight:841.8304Ru(OAc)2[(S)-binap]
CAS:Formula:C48H38O4P2RuColor and Shape:Light yellow to Amber to Dark green powder to crystalMolecular weight:841.85(S)-Ru(OAc)2(BINAP)
CAS:Controlled ProductFormula:C48H38O4P2RuColor and Shape:Off-WhiteMolecular weight:841.83
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