
CAS 3945-18-4: 3,4-Di-O-acetyl-L-arabinal
Formula:C9H12O5
InChI:InChI=1S/C9H12O5/c1-6(10)13-8-3-4-12-5-9(8)14-7(2)11/h3-4,8-9H,5H2,1-2H3/t8-,9+/m1/s1
InChI key:InChIKey=OWKCFBYWQGPLSJ-BDAKNGLRSA-N
SMILES:O(C(C)=O)[C@H]1[C@@H](OC(C)=O)COC=C1
Synonyms:- 2,3-di-O-acetyl-1,5-anhydro-4-deoxy-D-erythro-pent-4-enitol
- 3,4-Di-O-acetyl-<span class="text-smallcaps">L</span>-arabinal
- <span class="text-smallcaps">D</span>-erythro-Pent-4-enitol, 1,5-anhydro-4-deoxy-, 2,3-diacetate
- <span class="text-smallcaps">D</span>-erythro-Pent-4-enitol, 1,5-anhydro-4-deoxy-, diacetate
- <span class="text-smallcaps">L</span>-Arabinal 3,4-diacetate
- <span class="text-smallcaps">L</span>-erythro-Pent-1-enopyranose, 1,2-dideoxy-, diacetate
- Arabinal, 3,4-diacetate, <span class="text-smallcaps">L</span>-
- L-Arabinal 3,4-diacetate
- D-erythro-Pent-4-enitol, 1,5-anhydro-4-deoxy-, 2,3-diacetate
- Arabinal, 3,4-diacetate, L-
- L-erythro-Pent-1-enopyranose, 1,2-dideoxy-, diacetate
- See more synonyms
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Found 2 products.
3,4-Di-O-acetyl-L-arabinal
CAS:3,4-Di-O-acetyl-L-arabinal is a synthetic compound that belongs to the class of monofluorides. It has been synthesized from l-arabinose by a stereoselective process, with triflic acid as the catalyst and propargylation as the key step. The synthetic pathway starts from an acid hydrolysis of L-arabinose to yield 3,4-di-O-acetyl-L-arabinonic acid. This acid is then converted to 3,4 diacetyl L arabinonic acid with acetic anhydride and acetic acid in the presence of triethylamine. The final product is then obtained by reacting this intermediate with 1 equivalent of sodium fluoride in tetrahydrofuran (THF) using catalytic reduction with sodium borohydride at 0 °C. The major advantage of this synthetic process is that it provides two stereoisomers: (Formula:C9H12O5Purity:Min. 95%Color and Shape:Yellow Clear LiquidMolecular weight:200.19 g/mol