CAS 97239-80-0: 1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98% DiPPF

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

1,1'-Bis(diisopropylphosphino)ferrocene

1,1'-Bis(diisopropylphosphino)ferrocene is a paramagnetic compound that has the ability to bind to metal ions. It is commonly used in molecular structures as a potential and electrochemical probe. This ligand can also be used in coordination chemistry as a transition-metal complex. 1,1'-Bis(diisopropylphosphino)ferrocene is a reversible redox agent that exhibits cyclic voltammetry and cyclic behavior. The ferrocene moiety of this compound allows for the binding of other molecules and metals that have high affinity for it. When these are added, 1,1'-Bis(diisopropylphosphino)ferrocene becomes an efficient catalyst for many reactions.