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CAS 1028206-58-7: (SP-4-4)-[2-[2-(Amino-κN)etil]fenil-κC]cloro[diciclohexil(2',6'-dimetoxi[1,1'-bifenil]-2-il)fosfina-κP]paladio
Descripción:
La sustancia química conocida como "(SP-4-4)-[2-[2-(Amino-κN)etil]fenil-κC]cloro[diciclohexil(2',6'-dimetoxi[1,1'-bifenil]-2-il)fosfina-κP]paladio" con el número CAS 1028206-58-7 es un complejo de paladio que presenta un ligando fosfina quiral. Este compuesto se caracteriza por su coordinación de paladio con un ligando cloro y un ligando fosfina que contiene un grupo diciclohexilo y un moiety de bifenilo dimetoxilado. La presencia del grupo aminoetilfenilo contribuye a sus posibles aplicaciones en catálisis asimétrica, particularmente en reacciones como acilo cruzado e hidrogenación. La estereoquímica del compuesto es significativa, ya que puede influir en la reactividad y selectividad en procesos catalíticos. Además, la solubilidad, estabilidad y reactividad del complejo pueden verse afectadas por las propiedades estéricas y electrónicas de los ligandos unidos al centro de paladio. En general, este compuesto representa una clase especializada de química organometálica con utilidad potencial en la química orgánica sintética.
Fórmula:C34H45ClNO2PPd
InChI:InChI=1S/C26H35O2P.C8H10N.ClH.Pd/c1-27-23-17-11-18-24(28-2)26(23)22-16-9-10-19-25(22)29(20-12-5-3-6-13-20)21-14-7-4-8-15-21;9-7-6-8-4-2-1-3-5-8;;/h9-11,16-21H,3-8,12-15H2,1-2H3;1-4H,6-7,9H2;1H;/q;-1;;+2/p-1
Clave InChI:InChIKey=RUWSWVWKRCXWAA-UHFFFAOYSA-M
SMILES:[P](C1=C(C=CC=C1)C2=C(OC)C=CC=C2OC)([Pd+2]3([Cl-])[C-]=4C(CC[NH2]3)=CC=CC4)(C5CCCCC5)C6CCCCC6
Sinónimos:- (SP-4-4)-[2-[2-(Amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphine-κP]palladium
- Chloro(2-Dicyclohexylphosphino-2',6'-Dimethoxy-1,1'-Biphenyl)[2-(2-Aminoethylphenyl)]Palladium(Ii)
- Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)methyl-t-butylether adduct
- Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl(2',6'-dimethoxy[1,1'-biphenyl]-2-yl)phosphine-κP]-, (SP-4-4)-
- Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl(2′,6′-dimethoxy[1,1′-biphenyl]-2-yl)phosphine-κP]-, (SP-4-4)-
- SPhos Palladacycle
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Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butylether adduct
CAS:Fórmula:C34H45ClNO2PPdPureza:98%Forma y color:SolidPeso molecular:672.5734Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)
CAS:Producto controladoApplications Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) has been used as catalyst in, the studies of CDK 8/19 inhibitors: Discovery of novel and selective CDK8/19 dual inhibitors and elimination of their CYP3A4 time-dependent inhibition potential; Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination References Fujimoto J., et al., Bioorg. Med. Chem.: 25, 3018-3033 (2017); Arrechea P. L., et al., J. Am. Chem. Soc.: 138, 12486-12493 (2016)Fórmula:C26H35O2P·C8H10N·C5H12O·Cl·PdForma y color:NeatPeso molecular:760.721Chloro(2-Dicyclohexylphosphino-2,6-Dimethoxy-1,1-Biphenyl)[2-(2-Aminoethylphenyl)]Palladium(II)
CAS:Chloro(2-Dicyclohexylphosphino-2,6-Dimethoxy-1,1-Biphenyl)[2-(2-Aminoethylphenyl)]Palladium(II)Pureza:98%Peso molecular:672.57g/molChloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butylether adduct, min. 98% [SPhos Palladacycle Gen. 1]
CAS:Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) methyl-t-butylether adduct, min. 98% [SPhos Palladacycle Gen. 1]Fórmula:C34H45ClNO2PPdPureza:min. 98%Forma y color:white pwdr.Peso molecular:672.57Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II)
CAS:Producto controladoChloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) is a palladium complex that has anti-fungal activity. It works by binding to the fungal cell membrane and forming pores in it, which leads to cell death. This drug also inhibits the growth of cancer cells by inhibiting the synthesis of DNA and proteins. Chloro(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)[2-(2-aminoethylphenyl)]palladium(II) is metabolized by cytochrome P450 enzymes in mammalian cells, and can be modified by urea derivatives.Fórmula:C34H45ClNO2PPdPureza:Min. 95%Peso molecular:672.57 g/molRef: 3D-FC75208
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