CAS 12082-47-2: Bis(η2-eteno)(2,4-pentanodionato-κO,κO′)rodio
Descripción:
Bis(η²-eteno)(2,4-pentanodionato-κO,κO′)rhodio, comúnmente referido como complejo de rodio(II) bis(etileno), es un compuesto de coordinación que presenta al rodio como el ion metálico central. Este compuesto se caracteriza por su coordinación con dos ligandos de etileno, que están unidos al rodio a través de π-backbonding, lo que mejora su estabilidad y reactividad. Los ligandos de 2,4-pentanodiona actúan como quelantes bidentados, coordinándose al rodio a través de sus átomos de oxígeno, lo que contribuye a la estabilidad general del complejo. Este compuesto se utiliza típicamente en síntesis orgánica y catálisis, particularmente en reacciones que involucran olefinas. Su estructura única permite varios estados de oxidación y geometrías de coordinación, lo que lo convierte en un catalizador versátil en diversas transformaciones químicas. Además, la presencia de los ligandos de etileno puede facilitar la activación de pequeñas moléculas, como el hidrógeno, lo que lo hace útil en reacciones de hidrogenación. En general, este complejo de rodio es significativo en el campo de la química organometálica y la catálisis debido a sus propiedades distintivas y reactividad.
Fórmula:C9H15O2Rh
InChI:InChI=1S/C5H7O2.2C2H4.Rh/c1-4(6)3-5(2)7;2*1-2;/h3H,1-2H3;2*1-2H2;/q-1;;;+1
Clave InChI:InChIKey=JQAQEAYNENHVHZ-UHFFFAOYSA-N
SMILES:CC1=O[Rh+]23(O=C(C)[CH-]1)([CH2]=[CH2]2)[CH2]=[CH2]3
Sinónimos:- (Acetylacetonato)bis(ethylene)rhodium
- (Acetylacetonato)bis(η<sup>2</sup>-ethylene)rhodium
- 2,2,4,6-Tetramethyl-1,3$L3-Dioxa-2$L4-Rhodacyclohexa-3,5-Diene
- 2,4-Pentanedionatobis(ethylene)rhodium
- 2,4-Pentanedionatobis(ethylene)rhodium(I)
- Acetylacetonatobis(ethylene)rhodium(1)
- Bis(ethylene)(2,4-pentanedionato)rhodium
- Bis(ethylene)rhodium(I) acetylacetonate
- Bis(η<sup>2</sup>-ethene)(2,4-pentanedionato-κO,κO′)rhodium
- Bisethylenerhodium acetylacetonate
- Diethenylrhodium acetylacetonate
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Encontrado 10 productos.
Acetylacetonatobis(ethylene) rhodium(I)
CAS:Acetylacetonatobis(ethylene) rhodium(I) is a molecule that is part of the organometallic class of compounds. It has been shown to be an effective catalyst for the synthesis of acyl halides and styrene derivatives. This compound also has the ability to modulate the immune response in patients with idiopathic pulmonary fibrosis. The natural compounds found in this molecule have been shown to be effective at treating this disease by reducing inflammation and increasing lung function. Acetylacetonatobis(ethylene) rhodium(I) is an asymmetric catalyst that cleaves bonds with high stereoselectivity, making it useful for synthesizing molecules with specific chirality. This compound also binds to carbonyl groups, which are important for a variety of chemical reactions.Fórmula:C9H15O2RhPureza:Min. 95%Peso molecular:258.12 g/molRef: 3D-FA36865
Producto descatalogadoAcetylacetonatobis(ethylene)rhodium(I)
CAS:Producto controladoApplications Acetylacetonatobis(ethylene)rhodium(I) is a useful research chemical, a catalyst for the preparation and optical resolution of (tetramethyl)spirobiindane-diol and other useful research chemicals. References Lee, A., et al.: J. Org. Chem., 81, 3520 (2016); Zhou, Q., et al.: Synthesis (2018); Jung, H., et al.: Adv. Synth. Catal., 359, 3160 (2017)Fórmula:C9H11O2RhForma y color:NeatPeso molecular:254.088Acetylacetonatobis(ethylene)rhodium(I)
CAS:Fórmula:C9H15O2RhForma y color:Light yellow to Brown powder to crystalPeso molecular:258.12Acetylacetonatobis(ethylene)rhodium(I)
CAS:Pureza:95.0%Forma y color:SolidPeso molecular:258.12200927734375Acetylacetonatobis(ethylene)rhodium(I), 99%
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C9H15O2RhPureza:99%Forma y color:Crystalline powder or crystals, OrangePeso molecular:258.12Bis(ethylene)(2,4-pentanedionato)rhodium(I), Rh 39.9% min
CAS:It acts as a hydrogenation precursor. It is also used as intermediates which acts as catalyst such as in olefin hydroformylation. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C9H15O2RhPeso molecular:258.12Acetylacetonatobis(ethylene)rhodium(I)
CAS:Fórmula:C9H15O2RhPureza:98%Forma y color:SolidPeso molecular:258.1197Acetylacetonatobis(ethylene)rhodium(I), 98%
CAS:Acetylacetonatobis(ethylene)rhodium(I), 99%Fórmula:Rh(C2H4)2(C5H7O2)Pureza:98%Forma y color:yellow to orange xtl.Peso molecular:258.13Acetylacetonatobis(ethylene)?rhodium(I)
CAS:Acetylacetonatobis(ethylene)?rhodium(I)Pureza:98%+Peso molecular:258.12g/mol
