CAS 12150-46-8: 1,1'-bis(difenilfosfino)ferroceno
Descripción:
1,1'-Bis(difenilfosfino)ferroceno, con el número CAS 12150-46-8, es un compuesto organofosforado bimetálico caracterizado por su estructura única, que presenta un núcleo de ferroceno sustituido con dos grupos difenilfosfino. Este compuesto exhibe propiedades notables como alta estabilidad térmica y solubilidad en disolventes orgánicos, lo que lo hace útil en diversas aplicaciones químicas, particularmente en catálisis y química de coordinación. La presencia de la parte de ferroceno confiere un grado de actividad redox, permitiéndole participar en procesos de transferencia de electrones. Además, los grupos difenilfosfino mejoran su capacidad para coordinarse con metales de transición, facilitando la formación de complejos metálicos. Sus propiedades estéricas y electrónicas pueden ajustarse modificando los grupos fosfina, lo que puede influir en su reactividad y selectividad en reacciones catalíticas. En general, el 1,1'-bis(difenilfosfino)ferroceno es un compuesto valioso en la química sintética, particularmente en el desarrollo de nuevos catalizadores y materiales.
Fórmula:C34H28FeP2
InChI:InChI=1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/q2*-1;+2
Clave InChI:InChIKey=KZPYGQFFRCFCPP-UHFFFAOYSA-N
SMILES:P([C-]12[Fe+2]3456789([C-]%10(P(C%11=CC=CC=C%11)C%12=CC=CC=C%12)[CH]3=[CH]4[CH]5=[CH]6%10)[CH]1=[CH]7[CH]8=[CH]92)(C%13=CC=CC=C%13)C%14=CC=CC=C%14
Sinónimos:- 1,1'-Bis(diphenylphosphino)ferrocene
- 1,1'-Ferrocenebis(diphenylphosphine)
- 1,1'-Ferrocenediyl-bis(diphenylphosphine)
- 1,10-Bis(diphenylphosphanyl)ferrocene
- 1,1′-Ferrocendiylbis(diphenylphosphine)
- 1-Cyclopenta-2,4-Dienyl-Diphenyl-Phosphane Iron
- Bis(2-Diphenylphosphanylcyclopenta-2,4-Dien-1-Yl)Iron
- Dppf
- Ferrocene, 1,1′-bis(diphenylphosphino)-
- NSC 238923
- Phosphine, 1,1′-ferrocenediylbis[diphenyl-
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Encontrado 12 productos.
1,1’-Bis(diphenylphosphino)ferrocene
CAS:Producto controladoApplications Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which is a popular reagent for palladium-catalyzed coupling reactions. References Nataro, C., et al.: J. Chem. Ed., 86, 1412 (2009),Fórmula:C34H28FeP2Forma y color:NeatPeso molecular:554.381,1''-Bis(diphenylphosphino)ferrocene
CAS:Fórmula:C34H28FeP2Pureza:≥ 98.0%Forma y color:Yellow to dark yellow or orange powderPeso molecular:554.401,1'-Bis(diphenylphosphino)ferrocene, 99% DPPF
CAS:1,1'-Bis(diphenylphosphino)ferrocene, 99% DPPFFórmula:(C6H5)2PC5H4FeC5H4P(C6H5)2Pureza:99%Forma y color:yellow to orange xtl.Peso molecular:554.39DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%
CAS:Fórmula:C34H28FeP2Pureza:min. 98%Forma y color:Orange yellow, PowderPeso molecular:554.381,1'-Bis(diphenylphosphino)ferrocene
CAS:Fórmula:C34H28FeP2Pureza:>96.0%(T)Forma y color:Light yellow to Brown powder to crystalinePeso molecular:554.391,1'-Bis(diphenylphosphino)ferrocene, 97%
CAS:1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C34H28FeP2Pureza:97%Forma y color:Yellow to orange, Crystalline powder or powderPeso molecular:554.391,1'-Bis(diphenylphosphino)ferrocene, 98%
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C34H28FeP2Pureza:98%Forma y color:Orange, PowderPeso molecular:554.391,1'-Bis(diphenylphosphino)ferrocene
CAS:1,1'-Bis(diphenylphosphino)ferroceneFórmula:C34H28FeP2Pureza:98%Forma y color: yellow solidPeso molecular:554.38g/mol1,1'-Bis(diphenylphosphino)ferrocene
CAS:Fórmula:C34H28FeP2Pureza:97%Forma y color:SolidPeso molecular:554.3786421,1-Bis(diphenylphosphino)ferrocene
CAS:Used for palladium-catalyzed cross-coupling reactionsFórmula:C34H28FeP2Pureza:Min. 95%Forma y color:PowderPeso molecular:554.38 g/mol
