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CAS 12289-94-0: Rutenio II ciclooctadieno bis-(2,2,6,6-tetrametilheptanodionato)

Descripción:
Rutenio II ciclooctadieno bis-(2,2,6,6-tetrametilheptanodionato), comúnmente conocido como Ru(COD)(tmhd)2, es un compuesto de coordinación que presenta rutenio en un estado de oxidación +2. Este complejo se caracteriza por su coordinación con ciclooctadieno (COD) y dos ligandos bidentados, 2,2,6,6-tetrametilheptanoato (tmhd). La estructura típicamente exhibe una geometría cuadrada plana alrededor del centro de rutenio, que es común para complejos metálicos d6. La presencia de los voluminosos ligandos tmhd contribuye a la estabilidad y solubilidad del compuesto en disolventes orgánicos. Ru(COD)(tmhd)2 es notable por sus aplicaciones en catálisis, particularmente en síntesis orgánica y reacciones de polimerización, debido a su capacidad para facilitar diversas transformaciones. Además, puede exhibir propiedades electrónicas y ópticas interesantes, lo que lo convierte en un tema de investigación en ciencia de materiales. El compuesto generalmente se maneja con cuidado, al igual que muchos complejos metálicos, debido a la posible toxicidad y reactividad.
Fórmula:C16H26Ru
InChI:InChI=1/C8H12.2C4H7.Ru/c1-2-4-6-8-7-5-3-1;2*1-4(2)3;/h1-2,7-8H,3-6H2;2*1-2H2,3H3;/b2-1-,8-7-;;;/rC8H14Ru.C8H12/c1-7(2)5-9-6-8(3)4;1-2-4-6-8-7-5-3-1/h1,3,5-6H2,2,4H3;1-2,7-8H,3-6H2/b;2-1-,8-7-
SMILES:C=C(C)C[Ru]CC(=C)C.C1=CCCC=CCC1
Sinónimos:
  • Bis(2-Methylallyl)(1,5-Cyclooctadiene)Ruthenium(Ii)
  • Bis-(2-Methylallyl)Cycloocta-1,5-Diene Ruthenium (Ii) Complex
  • Bis(2-Methylallyl) (1,5-Cyclooctadiene)&
  • Bis(2-Methylallyl)(1,5-Cyclooctadiene)R&
  • RutheniumCyclooctadieneBis(2,2,6,6-Tetramethylheptanedionate)
  • Bis(2-Methylallyl)(1,5-Cyclooctadiene)Ruthenium(Ii),Min.
  • Bis-(2-methylallyl)cycloocta-1,5-diene ruthenium(II) complex, 30-32% Ru
  • Ruthenium cyclooctadiene bis(2,2,6,6-tetramethylheptanedionate)
  • Bis(2-Methylprop-2-Enyl)Ruthenium
  • (1Z,5Z)-cycloocta-1,5-diene
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Encontrado 7 productos.
  • Bis(2-methylallyl)(1,5-cycloocta­diene)ruthenium(II), min. 97%

    CAS:
    Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II), min. 97%
    Fórmula:(C4H7)2(C8H12)Ru
    Pureza:min. 97%
    Forma y color:tan to brown pwdr.
    Peso molecular:319.45

    Ref: 08-44-0046

    1g
    212,00€
    5g
    798,00€
    250mg
    73,00€
  • Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

    CAS:
    Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is a synthetic compound that belongs to the group of organometallic compounds. This compound is used as a catalyst in the preparative method of terminal alkynes, pentane, and transfer hydrogenation. Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) has been shown to be insoluble in water and organic solvents. It is also used as a ligand in Grignard reagents and as a catalyst for alcohols.
    Fórmula:C16H26Ru
    Pureza:Min. 95%
    Peso molecular:319.45 g/mol

    Ref: 3D-MAA28994

    5g
    Descatalogado
    10g
    Descatalogado
    Producto descatalogado
  • Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

    CAS:
    Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
    Fórmula:C16H26Ru
    Forma y color:Grey to cream to dark brown, Powder
    Peso molecular:319.45

    Ref: 02-H26891

    1g
    217,00€
  • Ruthenium II Cyclooctadiene Bis-(2,2,6,6-Tetramethylheptanedionate)

    CAS:
    Ruthenium II Cyclooctadiene Bis-(2,2,6,6-Tetramethylheptanedionate)
    Pureza:98%+
    Peso molecular:319.45g/mol

    Ref: 54-IN10585

    1g
    91,00€
    5g
    300,00€
    25g
    1.057,00€
    100g
    3.894,00€
    100mg
    32,00€
    250mg
    34,00€
  • Bis-(2-methylallyl)cycloocta-1,5-diene ruthenium(II) complex, 30-32% Ru

    CAS:
    This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
    Fórmula:C16H26Ru
    Forma y color:Crystalline powder, Beige to brown
    Peso molecular:319.45

    Ref: AC-29578

    1g
    Descatalogado
    250mg
    Descatalogado
    Producto descatalogado
  • Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

    CAS:
    Pureza:97%
    Peso molecular:298.123450196

    Ref: 10-F987323

    1g
    76,00€
    5g
    234,00€
    25g
    941,00€
    250mg
    69,00€
  • Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II)

    CAS:
    Fórmula:C16H26Ru
    Pureza:97%
    Forma y color:Solid
    Peso molecular:319.4476

    Ref: IN-DA003U5T

    1g
    116,00€
    5g
    246,00€
    100mg
    40,00€
    250mg
    57,00€