CAS 15243-33-1: dodecacarbonilo de triruteno
Descripción:
dodecacarbonilo de triruteno, con el número CAS 15243-33-1, es un compuesto organometálico compuesto por tres átomos de rutenio coordinados a doce ligandos de monóxido de carbono (CO). Este compuesto se caracteriza por su estructura de clúster, donde los átomos de rutenio están interconectados, formando un marco metálico estable. La presencia de ligandos de monóxido de carbono confiere una estabilidad y solubilidad significativas en disolventes orgánicos. dodecacarbonilo de triruteno es conocido por su papel en la catálisis, particularmente en reacciones que involucran monóxido de carbono e hidrocarburos, lo que lo hace de interés en la química sintética y aplicaciones industriales. Exhibe propiedades típicas de los carbonilos de metales de transición, como la capacidad de someterse a diversas reacciones de sustitución de ligandos y participar en procesos redox. Además, el compuesto puede ser sensible al aire y a la humedad, lo que requiere un manejo y almacenamiento cuidadosos en atmósferas inertes. Sus propiedades electrónicas y estructurales únicas lo convierten en un objeto de estudio en química de coordinación y ciencia de materiales.
Fórmula:C12O12Ru3
InChI:InChI=1S/12CO.3Ru/c12*1-2;;;
Clave InChI:InChIKey=NQZFAUXPNWSLBI-UHFFFAOYSA-N
SMILES:C(#O)[Ru]1(C#O)(C#O)(C#O)[Ru](C#O)(C#O)(C#O)(C#O)[Ru]1(C#O)(C#O)(C#O)C#O
Sinónimos:- Carbon Monooxide-Ruthenium (4:1)
- Dodecacarbonyl triruthenium
- Dodecacarbonyl-triangulo-triruthenium
- Dodecacarbonyltriruthenium
- Ruthenium carbonyl
- Ruthenium carbonyl (Ru3(CO)12)
- Ruthenium carbonyl (Ru<sub>3</sub>(CO)<sub>12</sub>)
- Ruthenium, dodecacarbonyltri-, triangulo
- Triangulo-Triruthenium dodecacarbonyl
- Trirutenio Dodecacarbonilo
- Triruthenium Dodecacarbonyle
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Encontrado 8 productos.
Triruthenium Dodecacarbonyl
CAS:Triruthenium dodecacarbonyl is a group p2 metal carbonyl. It has a thermal expansion of 5.5 x 10-6 K-1 and an enthalpy of formation of -12.7 kJ mol-1. This compound undergoes reactions with amines, resulting in the formation of diazonium salts. FTIR spectroscopy has been used to identify the presence of nitrogen atoms in this molecule, which are responsible for its strong absorption bands in the region between 3200 and 3400 cm-1. The carbonyl group found in triruthenium dodecacarbonyl reacts with fatty acids to produce tiglic acid, a chemical substance that can be used as a raw material for the production of synthetic ruthenium. Picolinic acid, a natural product found in plants, also reacts with triruthenium dodecacarbonyl and copper complex to form an ion pair knownFórmula:C12O12Ru3Pureza:Min. 95%Peso molecular:639.33 g/molTriruthenium dodecacarbonyl, 99%
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C12O12Ru3Pureza:99%Forma y color:Crystals, OrangePeso molecular:639.33Dodecacarbonyltriruthenium, 99%
CAS:A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF). This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C12O12Ru3Pureza:99%Peso molecular:639.33Triruthenium Dodecacarbonyl
CAS:Fórmula:C12O12Ru3Forma y color:Orange to Brown powder to crystalPeso molecular:639.33Ruthenium carbonyl, 99%
CAS:Ruthenium carbonyl, 99%Fórmula:Ru3(CO)12Pureza:99%Forma y color:orange xtl.Peso molecular:639.34Triruthenium dodecacarbonyl
CAS:Fórmula:C12O12Ru3Pureza:98%Forma y color:SolidPeso molecular:639.3312
