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CAS 176763-62-5: [[2,2′-[(1R,2R)-1,2-Ciclohexanodiylbis[(nitrilo-κN)metilideno]]bis[4,6-bis(1,1-dimetiletil)fenolato-κO]](2-)]cobalto
Descripción:
La sustancia química con el nombre "[[2,2′-[(1R,2R)-1,2-Ciclohexanodiylbis[(nitrilo-κN)metilideno]]bis[4,6-bis(1,1-dimetiletil)fenolato-κO]](2-)]cobalto" y el número CAS "176763-62-5" es un complejo de cobalto caracterizado por su estructura intrincada, que incluye un centro de cobalto coordinado a un sistema de ligandos bidentados. El ligando presenta un esqueleto de ciclohexanediyl, que proporciona un marco rígido, e incorpora grupos nitrilo que mejoran la coordinación con el ion de cobalto. Además, la presencia de grupos tert-butilo voluminosos en las unidades fenólicas contribuye a la hindrance estérica, influyendo en la solubilidad y reactividad del complejo. Este compuesto es de interés en la química de coordinación y puede exhibir propiedades catalíticas únicas o actividad biológica debido a su disposición específica de ligandos y centro metálico. Su estabilidad y reactividad pueden verse influenciadas por las propiedades electrónicas de los ligandos y el estado de oxidación del cobalto, lo que lo convierte en un tema de estudio en diversas aplicaciones químicas, incluida la catálisis y la ciencia de materiales.
Fórmula:C36H52CoN2O2
InChI:InChI=1S/C36H54N2O2.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;/h17-22,29-30,39-40H,13-16H2,1-12H3;/q;+2/p-2/t29-,30-;/m1./s1
Clave InChI:InChIKey=ZFWPDJKMASHRPT-GAQUOPITSA-L
SMILES:C(C)(C)(C)C1=C2[O-][Co+2]34[N]([C@]5([C@]([N]3=CC2=CC(C(C)(C)C)=C1)(CCCC5)[H])[H])=CC=6C([O-]4)=C(C(C)(C)C)C=C(C(C)(C)C)C6
Sinónimos:- (1R,2R)-(-)-N,N-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
- (R,R)-()-N,N-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
- (R,R)-(-)-N,N'-Bis(3,5-Di-Tert-Butylsalicylidene)-1,2-Cyclohexanediamino-Cobalt(Ii)
- (R,R)-(-)-N,N-bis(3,5-di-T-butylsalicylid -ene)-
- (R,R)-Co(salen)
- (R,R)-Jacobsen HKR catalyst
- (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminatocobalt(II)
- (SP-4-2)-[[2,2′-[(1R,2R)-1,2-Cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]cobalt
- 2,2'-{(1R,2R)-cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol)-cobalt (1:1)
- Cobalt, [[2,2′-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-κN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-κO]](2-)]-, (SP-4-2)-
- Cobalt, [[2,2′-[1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)phenolato]](2-)-N,N′,O,O′]-, [SP-4-2-(1R-trans)]-
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Encontrado 9 productos.
(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:Fórmula:C36H52CoN2O2Pureza:>95.0%(T)Forma y color:Red to Dark red powder to crystalPeso molecular:603.76(R,R)-N,N?-Bis(3,5-Di-Tert-Butylsalicylidene)-1,2-Cyclohexanediaminocobalt(II)
CAS:(R,R)-N,N?-Bis(3,5-Di-Tert-Butylsalicylidene)-1,2-Cyclohexanediaminocobalt(II)Pureza:98%Peso molecular:603.74g/mol(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:Pureza:99%Forma y color:SolidPeso molecular:603.336073904(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:Fórmula:C36H52CoN2O2Pureza:95%Forma y color:SolidPeso molecular:603.7434800000003(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(II)
CAS:(1R,2R)-(-)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)cobalt(II)Fórmula:C36H52CoN2O2Forma y color:red-brown pwdr.Peso molecular:603.76(R,R)-(-)-N,N'-Bis(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:Producto controladoFórmula:C36H52CoN2O2Forma y color:NeatPeso molecular:603.74(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:Fórmula:C36H52CoN2O2Peso molecular:603.76(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II), 98%
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C36H54CoN2O2Pureza:98%Forma y color:Powder, Orange to red-brownPeso molecular:605.77(R,R)-(-)-N,N'-Bis(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)
CAS:(R,R)-(-)-N,N'-Bis(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II) is a chiral ligand that is used in asymmetric synthesis. It can be prepared by the desymmetrization of (S,S)-(-)-N,N'-bis-(3,5-ditert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II). This compound has been found to be stable and enantioselective in catalytic reactions. The compound exhibits kinetic behavior with an orange color and a red solid state.Fórmula:C36H52CoN2O2Pureza:Min. 95%Peso molecular:603.74 g/molRef: 3D-FR138978
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