CAS 18531-94-7: (+)-BINOL
Descripción:
(+)-BINOL, o 1,1'-bi-2-naftol, es un compuesto orgánico quiral caracterizado por sus dos anillos de naftaleno conectados por un enlace simple con grupos hidroxilo en las posiciones 1 y 1'. Es un sólido incoloro a amarillo pálido que es poco soluble en agua pero soluble en disolventes orgánicos como el etanol y el éter. El compuesto exhibe una fuerte actividad óptica debido a su naturaleza quiral, lo que lo convierte en un bloque de construcción importante en la síntesis asimétrica y un ligando clave en varios procesos catalíticos. (+)-BINOL puede participar en enlaces de hidrógeno debido a sus grupos hidroxilo, influyendo en su reactividad e interacciones con otras moléculas. Se utiliza ampliamente en la síntesis de catalizadores quirales y en el desarrollo de reacciones enantioselectivas, particularmente en el campo de la química orgánica. Además, sus derivados pueden servir como precursores para compuestos orgánicos más complejos, mostrando su versatilidad en aplicaciones sintéticas.
Fórmula:C20H14O2
InChI:InChI=1S/C20H14O2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12,21-22H
Clave InChI:InChIKey=PPTXVXKCQZKFBN-UHFFFAOYSA-N
SMILES:OC1=C(C2=C(C=C1)C=CC=C2)C=3C4=C(C=CC3O)C=CC=C4
Sinónimos:- (+)-(1R)-[1,1'-Binaphthalene]-2,2'-diol
- (+)-(R)-2,2'-Dihydroxy-1,1'-binaphthyl
- (+)-1,1'-Bi-2-naphthol
- (+)-1,1'-Binaphthyl-2,2'-diol
- (+)-1,1′-Bis(2-naphthol)
- (+)-2,2'-Dihydroxy-1,1'-binaphthalene
- (+)-2,2'-Dihydroxy-1,1'-binaphthyl
- (+)-2,2'-Dihydroxy-1,1'-dinaphthyl
- (+)-2,2′-Binaphthol
- (+)-2,2′-Dihydroxydinaphthyl
- (+)-Bi-2-naphthol
- Ver más sinónimos
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Encontrado 10 productos.
(R)-(+)-1,1''-Bi-2-naphthol
CAS:Fórmula:C20H14O2Pureza:≥ 99.0%Forma y color:White to off-white powderPeso molecular:286.33(R)-(+)-1,1'-Bi(2-naphthol), 99%
CAS:It is used in biosynthetic preparation for enantioselective oxidation of naphthols to binaphthyldiols with horseradish peroxidase catalyst. A chiral auxiliary used in the catalytic asymmetric oxidation of sulfides to sulfoxides. Chiral lanthanide triflates formed from binaphthol serve as catalysts for asymmetric Diels-Alder reactions. Derivatives of binaphthol have recently found use in asymmetric Claisen rearrangements and asymmetric epoxidations.5 The lithium aluminum hydride derivative of these diols (BINAP-H) has been used extensively for the reduction of ketones. Chiral binapthol imminium salt precursor. Salts were used for an asymmetric epoxidation of olefins. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C20H14O2Pureza:99%Forma y color:White to cream or pale gray, Crystals or powder or crystalline powderPeso molecular:286.33R-(+)-1,1'-Bi-2-naphthol
CAS:Pureza:99.0%Forma y color:Solid, Crystalline PowderPeso molecular:286.33(R)-(+)-1,1'-Bi-2-naphthol, 99%
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C20H14O2Pureza:99%Forma y color:White to light beige, Crystalline powder or crystalsPeso molecular:286.33(R)-[1,1'-Binaphthalene]-2,2'-diol
CAS:Fórmula:C20H14O2Pureza:98%Forma y color:SolidPeso molecular:286.324(R)-1,1'-Bi-2-Naphthol
CAS:(R)-1,1'-Bi-2-Naphthol is an organic compound that is made from the hydrogenation of 2-naphthol. The sodium salts of this compound are chiral and can be used to synthesize racemic mixtures with a high degree of optical purity. The x-ray crystal structures of (R)-1,1'-Bi-2-Naphthol have been studied in detail and show that this molecule exhibits intermolecular hydrogen bonding interactions. It also has a steric interaction with the amine group which prevents rotation about the C3-C4 bond. Other interesting features include intramolecular hydrogen bonding interactions between the hydroxyl group and the alkanoic acid. This molecule also has a hydrophobic region consisting of three methyl groups that are connected to fatty acids.Fórmula:C20H14O2Pureza:Min. 98.5 Area-%Forma y color:White Off-White PowderPeso molecular:286.32 g/mol(R)-2,2'-Dihydroxy-[1,1']-binaphthyl
CAS:(R)-2,2'-Dihydroxy-[1,1']-binaphthylFórmula:C20H14O2Pureza:97%Forma y color: white powderPeso molecular:286.32g/molR-(+)-1,1'-Bi-2-Naphthol
CAS:Producto controladoApplications R-(+)-1,1'-Bi-2-Naphthol is used in biosynthetic preparation for enantioselective oxidation of naphthols to binaphthyldiols with horseradish peroxidase catalyst. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Sridhar, M., et al.: Tetrahedron Lett., 38, 5695 (1997)Fórmula:C20H14O2Forma y color:NeatPeso molecular:286.32(R)-(+)-1,1'-Bi-2-naphthol
CAS:Fórmula:C20H14O2Pureza:>98.0%(T)(HPLC)Forma y color:White to Light yellow powder to crystalPeso molecular:286.33R-(+)-1,1'-Bi-2-naphthol, 99% (R)-BINOL
CAS:R-(+)-1,1'-Bi-2-naphthol, 99% (R)-BINOLFórmula:HOC10H6C10H6OHPureza:99%Forma y color:white to off-white pwdr.Peso molecular:286.33
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