CAS 52522-40-4: Paladio, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-difenil-1,4-pentadien-3-ona]]di-, comp. con triclorometano (1:1)
Descripción:
Paladio, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-difenil-1,4-pentadien-3-ona]]di-, comp. con triclorometano (1:1) es un compuesto de coordinación que presenta paladio como el ion metálico central coordinado a un ligando específico derivado de una estructura de diphenil-pentadienona. El compuesto exhibe características típicas de los complejos de paladio, incluida la posible actividad catalítica, particularmente en transformaciones orgánicas. La presencia del disolvente tricloroetano indica que el compuesto puede ser soluble en disolventes orgánicos, lo cual es común en muchos complejos metal-orgánicos. Los ligandos en este compuesto probablemente impartan propiedades electrónicas y estéricas únicas, influyendo en su reactividad y estabilidad. Además, el compuesto puede exhibir propiedades ópticas interesantes debido al sistema conjugado presente en los ligandos. Al igual que muchos complejos de paladio, puede ser de interés en campos como la catálisis, la ciencia de materiales y la síntesis orgánica, donde el paladio se utiliza a menudo por su capacidad para facilitar diversas reacciones químicas. Se deben observar precauciones de seguridad y manejo debido a la posible toxicidad de los compuestos de paladio y del tricloroetano.
Fórmula:C51H42O3Pd2·CHCl3
InChI:InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-16;2-1(3)4;;/h3*1-14H;1H;;
Clave InChI:InChIKey=LNAMMBFJMYMQTO-UHFFFAOYSA-N
SMILES:O=C1[CH]=2[Pd]345([CH](=[CH]3C6=CC=CC=C6)C(=O)[CH]=7[Pd]89([CH]1=[CH]8C%10=CC=CC=C%10)([CH](C(=O)[CH]4=[CH]5C%11=CC=CC=C%11)=[CH]9C%12=CC=CC=C%12)[CH]7C%13=CC=CC=C%13)[CH]2C%14=CC=CC=C%14.C(Cl)(Cl)Cl
Sinónimos:- 1,2,4,5-Pentanetetrayl, 3-Oxo-1,5-Diphenyl-, Compd. With Trichloromethane, Palladium Salt (3:1:2)
- 1,4-Pentadien-3-one, 1,5-diphenyl-, palladium complex, (E,E)-
- Dipalladium(0)tris(dibenzylideneacetone)-chloroform adduct
- Dipalladiumtris(dibenzylideneacetone) chloroform adduct
- Methane, trichloro-, compd. with (all-E)-tris[μ-[(1,2-η:4,5-η)-1,5-diphenyl-1,4-pentadien-3-one]]dipalladium (1:1)
- Methane, trichloro-, compd. with tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]dipalladium (1:1)
- Palladium, tris[μ-[(1,2-η:4,5-η)-(1E,4E)-1,5-diphenyl-1,4-pentadien-3-one]]di-, compd. with trichloromethane (1:1)
- Palladium, tris[μ-[(1,2-η:4,5-η)-1,5-diphenyl-1,4-pentadien-3-one]]di-, (all-E)-, compd. with trichloromethane (1:1)
- Pd<sub>2</sub>(dba)<sub>3</sub>.CHCl<sub>3</sub>
- Tris(dibenzylideneacetone)dipalladium chloroform
- Tris(dibenzylideneacetone)dipalladium-chloroform (1:1)
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Encontrado 9 productos.
Tris(dibenzylideneacetone)dipalladium(0), complex with chloroform, Pd 20.6%
CAS:Tris(dibenzylideneacetone)dipalladium(0) is used in Synthesis of nanosized palladium phosphides upon interaction with white phosphorous, Preparation of palladium triphenylphosphine carbonyl cluster complexes, Precursor for synthesis of functionalized multiwalled carbon nanotube-palladium complexes used as catalysts for Heck coupling reactions. This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C52H43Cl3O3Pd2Peso molecular:1035.10Tris(Dibenzylideneacetone)dipalladium (0)chloroform adduct
CAS:Pureza:98.0%Forma y color:SolidPeso molecular:1035.0999755859375Tris(dibenzylideneacetone)dipalladium chloroform adduct
CAS:Tris(dibenzylideneacetone)dipalladium chloroform adductPureza:98%Forma y color:Dark Brown Black PowderPeso molecular:1,035.10g/molTris(dibenylideneacetone)dipalladium-chloroform
CAS:Fórmula:C52H43Cl3O3Pd2Pureza:98%Forma y color:SolidPeso molecular:1035.095Tris(Dibenzylideneacetone)Dipalladium-Chloroform Adduct extrapure, 20% Pd
CAS:Fórmula:C52H43Cl3O3PdPeso molecular:1035.1Tris(dibenzylideneacetone)dipalladium(0)-chloroform Adduct
CAS:Producto controladoFórmula:C52H43Cl3O3Pd2Forma y color:NeatPeso molecular:1035.1Tris(dibenzylideneacetone)dipalladium(0) chloroform adduct
CAS:Tris(dibenzylideneacetone)dipalladium(0) chloroform adductFórmula:(C6H5CHCHCOCHCHC6H5)3Pd2·CHCl3Forma y color:red to brown solidPeso molecular:1035.08Tris(dibenzylideneacetone)dipalladium-chloroform adduct, 97%
CAS:This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.Fórmula:C52H43Cl3O3Pd2Pureza:97%Forma y color:Purple to black, Crystalline powderPeso molecular:1035.10Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct
CAS:Producto controladoTris(dibenzylideneacetone)dipalladium (0)-chloroform adduct is a catalyst that is used in cross-coupling reactions. It is an efficient method for the preparation of β-unsaturated ketones, which are important intermediates in organic synthesis. The catalytic cycle involves hydrolysis and condensation reactions. Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct can be prepared by reacting chloroform with a palladium compound in the presence of silver trifluoromethanesulfonate and a diphosphine ligand. The product contains a chloroform molecule that can be replaced by other functional groups such as chloride, fatty acid, or imine nitrogen. Tris(dibenzylideneacetone)dipalladium (0)-chloroform adduct has been characterized by x-ray crystal structures to identifyFórmula:C51H42O3Pd2·CHCl3Pureza:Min. 95%Forma y color:PowderPeso molecular:1,035.09 g/mol
