2-(Trimethylsilyl)ethanesulfonylchloride
CAS:
Rif. 3D-FT149708
Informazioni sul prodotto
Nome:2-(Trimethylsilyl)ethanesulfonylchloride
Marchio:Biosynth
Descrizione:2-(Trimethylsilyl)ethanesulfonylchloride is a n-oxide that can be used for the synthesis of aziridines. It is prepared by the reaction of triphenylphosphine and protonated trimethylsilyl chloride in the presence of amines. The reaction proceeds via an ionic mechanism, which involves the formation of a cationic adduct followed by a nucleophilic attack on the phosphorus atom. The asymmetric synthesis of 2-(trimethylsilyl)ethanesulfonylchloride is achieved through sulfonation and subsequent treatment with sodium nitrite. This method affords two different enantiomers, both are active as chiral auxiliaries in organic synthesis.
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Proprietà chimiche
Peso molecolare:200.76 g/mol
Formula:C5H13ClO2SSi
Purezza:Min. 95%