POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 30-45 cSt
CAS:
Rif. 3H-HMS-993
3kg
Prezzo su richiesta
100g
Prezzo su richiesta
18kg
Prezzo su richiesta
200kg
Prezzo su richiesta
1000kg
Prezzo su richiesta
Informazioni sul prodotto
Nome:POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 30-45 cSt
Marchio:Gelest
Descrizione:Siloxane-Based Silane Reducing Agent
Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.
Pendant Functional Fluid; polyMethylHydrosiloxanes, TMS Terminated
MethylHydrosiloxane homopolymers are used as water-proofing agents, reducing agents and as components in some foamed silicone systems.
Poly(methylhydrosiloxane); Methyl hydrogen siloxane; Polysiloxanes, methyl hydrogen; Siloxanes and silicones, methyl hydrogen
Viscosity: 30-45 cStMolecular Weight: 2,100-2,400 g/molMol% Hydride: 100Reduces lactones to lactolsReduces aldehydes, ketones, esters, lactones, triglycerides and epoxides to alcohols with zinc hydride catalysisWith titanium tetraisopropoxide catalysis carries out reductive amination of ketones and aldehydes and the reduction of acids or esters to 1° alcoholsWith TBAF catalysis selectively reduces aldehydes over ketonesUsed to generate tri-n-butyltin hydride ‘in-situ’ and in a one-pot hydrostannylation/Stille coupling sequenceReduces esters to alcoholsExtensive review of silicon based reducing agents: Larson, G.; Fry, J. L. "Ionic and Organometallic-Catalyzed Organosilane Reductions", Wipf, P., Ed.; Wiley, 2007
Avviso:I nostri prodotti sono destinati esclusivamente ad uso di laboratorio. Per qualsiasi altro utilizzo, vi preghiamo di contattarci.
Proprietà chimiche
Peso molecolare:2100-2400
Colore/Forma:Liquid
Richiesta tecnica su: POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 30-45 cSt
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