9-Phosphabicyclononanes (mixture of isomers) in toluene
CAS:
Ref. 3D-FP168306
250g
346.00€
500g
502.00€
Product Information
Name:9-Phosphabicyclononanes (mixture of isomers) in toluene
Brand:Biosynth
Description:9-Phosphabicyclo[3.3.1]nonane (9-PBN) is the simplest member of a class of phosphorus compounds that can be used as an efficient and economical reagent for cross-coupling reactions in organic synthesis. 9-PBN is a stable, white solid that is soluble in hydrocarbon solvents and reacts with nucleophiles such as amines, alcohols, and thiols to form phosphine oxides (PR 3 ). 9-PBN undergoes rapid isomerization between the cis and trans configurations at room temperature. When heated, it converts to the cis configuration at a rate that depends on the activation energy of the reaction. It has been proposed that this conversion may be catalyzed by acid or base catalysis because of its acidic nature or polydentate ligand properties. 9-PBN has been shown to react with primary alcohols to form amides via nucleophilic attack on
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Chemical properties
Molecular weight:142.18 g/mol
Formula:C8H15P
Purity:Min. 95%
Color/Form:Powder
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