POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 30-45 cSt
CAS:
Ref. 3H-HMS-993
3kg
To inquire
100g
To inquire
18kg
To inquire
200kg
To inquire
1000kg
To inquire
Product Information
Name:POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 30-45 cSt
Brand:Gelest
Description:Siloxane-Based Silane Reducing Agent
Organosilanes are hydrocarbon-like and possess the ability to serve as both ionic and free-radical reducing agents. These reagents and their reaction by-products are safer and more easily handled and disposed than many other reducing agents. The metallic nature of silicon and its low electronegativity relative to hydrogen lead to polarization of the Si-H bond yielding a hydridic hydrogen and a milder reducing agent compared to aluminum-, boron-, and other metal-based hydrides. A summary of some key silane reductions are presented in Table 1 of the Silicon-Based Reducing Agents brochure.
Pendant Functional Fluid; polyMethylHydrosiloxanes, TMS Terminated
MethylHydrosiloxane homopolymers are used as water-proofing agents, reducing agents and as components in some foamed silicone systems.
Poly(methylhydrosiloxane); Methyl hydrogen siloxane; Polysiloxanes, methyl hydrogen; Siloxanes and silicones, methyl hydrogen
Viscosity: 30-45 cStMolecular Weight: 2,100-2,400 g/molMol% Hydride: 100Reduces lactones to lactolsReduces aldehydes, ketones, esters, lactones, triglycerides and epoxides to alcohols with zinc hydride catalysisWith titanium tetraisopropoxide catalysis carries out reductive amination of ketones and aldehydes and the reduction of acids or esters to 1° alcoholsWith TBAF catalysis selectively reduces aldehydes over ketonesUsed to generate tri-n-butyltin hydride ‘in-situ’ and in a one-pot hydrostannylation/Stille coupling sequenceReduces esters to alcoholsExtensive review of silicon based reducing agents: Larson, G.; Fry, J. L. "Ionic and Organometallic-Catalyzed Organosilane Reductions", Wipf, P., Ed.; Wiley, 2007
Notice:Our products are intended for lab use only. For any other use, please contact us.
Chemical properties
Molecular weight:2100-2400
Color/Form:Liquid
Technical inquiry about: POLYMETHYLHYDROSILOXANE, TRIMETHYLSILYL TERMINATED, 30-45 cSt
Please use instead the cart to request a quotation or an order
If you want to request a quotation or place an order, please instead add the desired products to your cart and then request a quotation or order from the cart. It is faster, cheaper, and you will be able to benefit from the available discounts and other advantages.