POTASSIUM TRIMETHYLSILANOLATE, 95%
CAS:
Ref. 3H-SIP6901.0
Product Information
Name:POTASSIUM TRIMETHYLSILANOLATE, 95%
Brand:Gelest
Description:Silane Cross-Coupling Agent
The cross-coupling reaction is a highly useful methodology for the formation of carbon-carbon bonds. It involves two reagents, with one typically being a suitable organometallic reagent - the nucleophile - and the other a suitable organic substrate, normally an unsaturated halide, tosylate or similar - the electrophile.
Potassium trimethylsilanolate; Potassium trimethylsiloxide; Trimethylsilanol, potassium salt
Contains potassium hydroxide, hexamethyldisiloxaneCatalyst for the cross-coupling of aryl and vinylsilanesInitiates silicone (cyclic siloxane) polymerizationsCleaves esters under non-aqueous conditionsCatalyzes fluoride-free, silicon-based cross-coupling reactionsConverts difluorobenzenes to fluorophenolsExtensive review of silicon based cross-coupling agents: Denmark, S. E. et al. "Organic Reactions, Volume 75" Denmark, S. E. ed., John Wiley and Sons, 233, 2011
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Chemical properties
Molecular weight:128.29
Formula:C3H9KOSi
Purity:95%
Color/Form:Solid