(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol
CAS:
Ref. TR-D480025
50mg
178.00€
100mg
266.00€
250mg
509.00€
Product Information
Name:(1R,3R,4R)-(-)-3,5-Dinitrobenzoate Menthol
Controlled Product
Synonyms:
- 7-[(2S,5R)-6-[[tert-butyl(diphenyl)silyl]oxymethyl]-3,4,5-trihydroxyoxan-2-yl]oxy-4-methylchromen-2-one
Brand:TRC
Description:Applications (1S,3S,4S)-(-)-3,5-dinitrobenzoate Menthol is an intermediate in the synthesis of (±)-Neoisomenthol (N389960) which is a useful synthetic intermediate. It is used to prepare alkyl and aryl esters by chemoselective acylation of alkyl and aryl alcohols with carboxylic acid anhydrides in the presence of magnesium bis(trifluoromethylsulfonyl)amide under solvent-free conditions.
References Chakraborti, A., et al.: J. Org. Chem., 71, 5785 (2006)
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Chemical properties
Molecular weight:576.709
Formula:C32H36O8Si
Color/Form:Neat
InChI:InChI=1S/C32H36O8Si/c1-20-17-27(33)39-25-18-21(15-16-24(20)25)38-31-30(36)29(35)28(34)26(40-31)19-37-41(32(2,3)4,22-11-7-5-8-12-22)23-13-9-6-10-14-23/h5-18,26,28-31,34-36H,19H2,1-4H3/t26?,28-,29?,30?,31+/m0/s1
InChI key:InChIKey=YTHDSJIOVBDTQV-OFMPIAEOSA-N
SMILES:Cc1cc(=O)oc2cc(O[C@@H]3OC(CO[Si](c4ccccc4)(c4ccccc4)C(C)(C)C)[C@H](O)C(O)C3O)ccc12
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