2-(Trimethylsilyl)ethanesulfonylchloride
CAS:
Ref. 3D-FT149708
Informação sobre produto
Nome:2-(Trimethylsilyl)ethanesulfonylchloride
Marca:Biosynth
Descrição:2-(Trimethylsilyl)ethanesulfonylchloride is a n-oxide that can be used for the synthesis of aziridines. It is prepared by the reaction of triphenylphosphine and protonated trimethylsilyl chloride in the presence of amines. The reaction proceeds via an ionic mechanism, which involves the formation of a cationic adduct followed by a nucleophilic attack on the phosphorus atom. The asymmetric synthesis of 2-(trimethylsilyl)ethanesulfonylchloride is achieved through sulfonation and subsequent treatment with sodium nitrite. This method affords two different enantiomers, both are active as chiral auxiliaries in organic synthesis.
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Propriedades químicas
Peso molecular:200.76 g/mol
Fórmula:C5H13ClO2SSi
Pureza:Min. 95%