Pesticide Standards

Applications (E)-(5,6-Dihydro-1,4,2-dioxazin-3-yl)[2-[(tetrahydro-2H-pyran-2-yl)oxy]phenyl]-methanone O-Methyloxime-d4 is an intermediate used in the synthesis of Fluoxastrobin-d4 (F596702), which is a labelled Fluoxastrobin (F596700). Leaf-systemic broad-spectrum fungicide for use in cereal and food crops; member of methoxy-imiodihydro-dioxazines. Agricultural fungicide. References Milus, E., et al.: Plant Dis., 78, 697 (1994), D'Mello, J., et al.: Eur. J. Plant Pathol., 104, 745 (1998), Domijan, A., et al.: Food Addit. Contam., 22, 677 (2005),

Applications 4-isopropylaniline is a useful synthetic intermediate. It is a metabolite of phenylurea herbicide isoproturon. It was used in the hydroamination of phenylacetylene. References Peeters, A., et al.: Audio, Transactions of the IRE Professional Group on, 47, 4114 (2011); Sørensen, S., et al.: Pest Manag. Sci., 59, 1118 (2003)

Applications A glucuronide metabolite of Chlorpyrifos (C425300). References Barron, M.G., et al.: Environ. Toxicol. Chem., 12, 1469 (1993), Tang, J., et al.: Drug Metab. Dispos., 29, 1201 (2001),

Applications Tefluthrin is a pyrethroid based insecticide. Tefluthrin is used in the control of a broad range of soil pests, including members of the Coleoptera, Lepidoptera, and Diptera. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References McDonald, E. et al.: Bright. Crop Prot. Conf. Pest Dis., 3, 1143 (1986); Jutsum, A.R. et al.: Bright. Crop Prot. Conf.

Applications Phorate is a non-biocumulative organophosphate used as an insecticide and acaricide. Phorate is an inhibitor of acetylcholinesterase and pseudocholinesterase. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Pandey, G.C. et al.: Ind. J. Comp. Anim. Physiol., 6, 1 (1988); Henderson, M.C. et al.: Biochem. Pharmacol., 68, 959 (2004); Peter, J.V. et al.: NeuroToxicology, 29, 335 (2008);

Applications 1,1,2,3,4,5,6-Heptachlorocyclohexane is an organochloride which is one of the isomers of hexachlorocyclohexane and is an byproduct of insecticide Lindane (L465990). Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Bist, R., et al.: Int. J. Pharm. Pharma. Sci., 4, 117 (2012); Heinz, M., et al.: Human. Health. Handbook., 1, 355 (2012); Bay, S.M., et al.: Enviro. Toxciol. Chem., 31, 2711 (2012);

Applications Phosalone is a organophosphate compouund used as insecticide and acaricide. Phosalone is a weak inhibitor of acetylcholinesterase. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Munj, A.Y., et al.: Pestol., 36, 35 (2012); Andrascikova, M., et al.: Food. Add. Contamin. Chem. Anal. Control. Exposure. Risk. Assess., 30, 286 (2013);

Applications Cyflumetofen is a novel acaricide that only affects spider mites. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Hayashi, N., et al.: Pest Manag. Sci., 69, 1080 (2013); Van Leeuwen, T., et al.: Pestic. Biochem. Physiol., 121, 12 (2015);

Applications 1-Chloro-4-[(methylsulfonyl)methyl]benzene is a metabolite of the pesticide benthiocarb (T344255). References Ishikawa, K., et al.: Nippon Noyaku Gakkaishi, 1, 49 (1976); Ishii, Y., et al.: Dokl. Soobshch. - Mezhdunar. Kongr. Zashch. Rast., 8th, 3, 223 (1975); Duah-Yentumi, S., et al.: Soil Sci. Plant Nutr., 26, 541 (1980)

Applications A metabolite of herbicide Diuron (D494415) and Linuron (L468500). It was investigated in wheat and radish. References Field, J., et al.: J. Agric. Food Chem., 45, 3897 (1997),

Applications 5-Chloro Imidacloprid is an impurity of Imidacloprid (I274990), a neonicotinoid; the active ingredient in certain neuro-active insecticides. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Kagabu, S., et al.: J. Pesticide. Sci., 31, 150 (2006); Sung, N.D., et al.: Sung, N.D., et al.: Bull. Korean. Chem. Soc., 27, 1741 (2006); Tomizawa, M., et al.: J. Med. Chem., 52, 3735 (2009); Chem. and Eng. News 90: 10 (2012)

Applications A pyridine derivative used in the preparation of anti-ulcerative agents and other pharmaceutical compounds. References Kuehler, T.C. et al.: J. Med. Chem., 38, 4906 (1995);

Applications 4,4'-Dibromobenzophenone is a reagent used in the synthesis of polyelectrolytes which serve as fluorescent visualizers for intracellular imaging with good biocompatibility. References Hu, R., et al.: Chem. Asian J., 8, 2436-2445 (2013)

Applications: 3-Mesityl-2-oxo-1-oxaspiro[4.4]non-3-en-4-ol, is the metabolite of Spiromesifen, which is a Spirocyclic Tetronic Acid, environmentally friendly and novel structural pesticide. Dangerous Goods Info: Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Jin-Hao, Zh., et al.: Pest Management Science, 68, 10 (2012);

Applications bis(8-Quinolinolato-κN1,κO8)-Copper is a disinfectant for vegetables. High polarity pesticide. References Li, Z., et al.: Anal. Lett., 49, 737-743 (2016); Kim, H. S., et al.: Organohalog. Compd., 75, 359-362 (2013)

Applications 4,4'-Dichlorodiphenyltrichloroethane - D8 is a synthetic organochlorine insecticide. 4,4'-Dichlorodiphenyltrichloroethane - D8 functions by opening sodium ion channels in the insects’ neurons, causing them to fire spontaneously which in turn leads to death. 4,4'-Dichlorodiphenyltrichloroethane - D8 is banned for agricultural use in North America, it is still commonly used in some countries and particularly as a means of malaria control. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Balkew, M. et al.: Paras. Vect., 3, No pp. given (2010); Kikankie, C.K. et al.: Malaria J., 9, No pp. given. (2010); Battu, R.S. et al.: Sci. Total Environ., 78, 173 (1989).

Applications Chinomethionate is a quinoxaline fungicide. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Speck-Planche, A., et al.: Ectoxicol. Environ. Safety, 80, 308 (2012); Stensvand, A., et al.: J. Agri. Food Chem., 48, 917 (2000)

Applications Quintrione is herbicidal compound comprising Heterocyclic Amide compound and use thereof. References Wang, Z., et al.:PCT Int. Appl., (2020);

Applications Selective herbicide. Potential symptoms of overexposure are irritation of eyes and skin; dermatitis, skin sensitization; dyspnea, weakness, incoordination, salivation; hypothermia; liver injury.This compound is a contaminant of emerging concern (CECs) Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Dalgaard-Mikkelsen, S., et al.: Pharmacol. Rev., 14, 225 (1962), Muller, K., et al.: J. Environ. Qual., 31, 309 (2002), Backhaus, T., et al.: Environ. Toxicol. Chem., 23, 258 (2004),

Applications Metolachlor is an acyanilide herbicide similar to selective pre-emergence herbicides (1). It is a contaminant in the groundwater and potential pollutant (2). This compound is a contaminant of emerging concern (CECs). Drinking water contaminant candidate list 3 (CCL 3) compound as per United States Environmental Protection Agency (EPA), environmental, and food contaminants. References 1. McGahen, L. et al.: J. Agric. Food Chem. 1978 26 (2), pp 414–4192. Chesters, G. et al.: Rev. Environ Contam Toxicol. 1989;110:1-74.

Stability Moisture Sensitive, Unstable in Solution Applications Bensulfuron-methyl inhibits the growth of Anabaena azotica. ALS inhibitor. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Liao, J. Z., et al.: Fresenius Environ. Bull., 25, 5000 (2016)

Stability Very Hygroscopic Applications The major labelled metabolite of Glufosinate (G596950), used as herbicide. References Royer, A., et al.: Anal. Chem., 72, 3826 (2000), Muller, B., et al.: Pestic. Manag. Sci., 57, 46 (2001), Duke, S., et al.: J. Agric. Food Chem., 51, 340 (2003),

Applications A labelled metabolite of Atrazine (ATR) (A794600). References Compton, D., et al.: Eur. J. Pharmacol., 110, 157 (1985), Das, P., et al.: Toxicol. Sci., 59, 127 (2001), Das, P., et al.: Life Sci., 73, 3123 (2003), Coban, A., et al.: J. Neurochem., 100, 1177 (2007),

Stability Hygroscopic Applications Organic reagent used to synthesize phthalates. References Duchowicz, P.R., et al.: Bioorg. Med. Chem., 16, 7944 (2008), di Luccio, E., et al.: Biochem., 47, 4039 (2008), Lopez, Z., et al.: App. Microbiol. Biotechnol., 78, 739 (2008), Hong, Y., et al.: Toxicol. Lett., 184, 139 (2009),

Applications Desethyldesisopropyl Atrazine is a metabolite of Atrazine (A794600). References Adams, N., et al.: J. Agric. Food Chem., 38, 1411 (1990), Abbas, R., et al.: Toxicol. Appl. Pharmacol., 147, 15, (1997), Cooper, R., et al.: Toxicol. Sci., 2000, 53, 297 (2000), Hossain, M., et al.: Toxicology, 248, 52 (2008),

Applications Cyclanilide is a plant growth regulator that functions by interactting with auxin-regulated processes. Cyclanilide is commonly used on cotton plants to either suppress vegetative growth or accelerate senescence. Cyclanilide is also used as a bioregulator of deciduous fruit trees. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Burton, J. et al.: Proc. Plant Growth Reg. Soc. Am., 36, 56 (2009); Burton, J. et al.: J. Plant Growth Reg., 27, 342 (2008); Elfving, D.C. et al.: Act Horticul., 884, 159 (2010);

Applications Plifenat is a widely used pesticide. Also, it is analog of DDT, one of the organochlorine pesticides, widely used in agricultural and mosquito sprayings. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Kang, L., et al.: RSC Adv., 5, 117, (2015); Kang, L., et al.: Atmospheric Environ., 103, 357-364 (2015)

Applications Terbuthylazine-(ethyl-d5) is the deuterized or labeled form of Terbuthylazine (T110500), which is a triazine herbicide. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Schenck, F., et al.: Bull Environ. Contam. Toxicol., 73, 24 (2004)

Stability Light Sensitive Applications α-Chlordane is an organochlorine pesticide/insecticide used in the protection of crops from pests. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Shoeib, M., et al.: Env. Toxicol. Chem., 21, 984 (2002); Parlar, H. et al.: J. Agric. Food. Chem., 27, 278 (1979);

Applications Glyphosate-13C,15N is the labelled analogue of Glyphosate (G765000), which is used as a herbicide. References Davis, V., et al.: Weed Sci., 57, 494 (2009), Bellaloui, N., et al.: J. Agric. Food Chem., 57, 9050 (2009),

Applications A toxic metabolite of Phenacetin (P294580) which exhibits high renal toxicity. p-Phenetidine also reduced COX-1 and COX-2 expression in neutrophils. References Green, C., et al.: Br. Med. J., 1, 162 (1969), Nelson, S., et al.: J. Med. Chem., 25, 753 (1982), Nicholls, A., et al.: Xenobiotica, 27, 1175 (1997),

Applications 2,4,5-Trichlorophenoxyacetic Acid-d5 is an isotope labelled analog of 2,4,5-Trichlorophenoxyacetic Acid. It is suitable for plant cell culture tested. Post-emergence herbicide. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Smith, J., et al.: Science, 203, 1090 (1979), Salunkhe, C., et al.: Plant Cell Reports, 18, 670 (1999), Jheng, F., et al.: Plant Sci., 170, 1133 (2006),

Applications Oxyquinoline Sulfate is used as a food preservative. References Gendy, A. et al.: Aud. J. Basic. App. Sci., 6, 260 (2012); Abou El-Ghait, E. et al.: Res. J. Agri. Biol. Sci., 8, 261 (2012);

Applications Agricultural fungicide. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Corrales, M., et al.: Food Chem. Toxicol., 48, 3471 (2010), Lagunas-Allue, L., et al.: Anal. Bioanal. Chem., 398, 1509 (2010), Wong, J., et al.: J. Agric. Food Chem., 58, 5897 (2010),

Applications Thiosultap Sodium Salt is used as an insecticide. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Yan, X., et. al.: J. Plant Diseases Protection, 119, 152 (2012)

Applications Isotope labelled Metamidophos (M258840) is an organophosphate insecticide used in great quantities in rice fields in rice-producing countries. References Sipes, N.S., et al.: Chem. Res. Toxiciol., 26, 878 (2013); Mineau, P., et al.: Environ. Toxicol. Pharmacol., 34, 416 (2012);

Applications Metamidophos is an organophosphate insecticide used in great quantities in rice fields in rice-producing countries. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Sipes, N.S., et al.: Chem. Res. Toxiciol., 26, 878 (2013); Mineau, P., et al.: Environ. Toxicol. Pharmacol., 34, 416 (2012);

Applications A metabolite of Fenthion (FEN). Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Buratti, F., et al.: Toxicol. Lett., 167, 245 (2006), Buratti, F., et al.: Drug Metab. Dispos., 33, 295 (2005), Buratti, F., et al.: Toxicology, 241, 33 (2007),

Stability Hygroscopic Applications Methomyl is a carbamate insecticide. Useful in cannabis testing kits as a component of pesticide mixes (P698240). Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Armes, N., et al.: Bull. Entomol. Res., 86, 499 (1996); Shono, T., et al.: Pest. Biochem. Physiol., 75, 1 (2003)

Applications Labelled 2,4'-Dichlorodiphenyltrichloroethane (D434205). 2,4'-Dichlorodiphenyltrichloroethane is a chlorinated organic pesticide having estrogenic activity. Not a dangerous good if item is equal to or less than 1g/ml and there is less than 100g/ml in the package References Iwata, H., et al.: Environ. Sci. Technol., 27, 1080 (1993), Beyer, A., et al.: Environ. Toxicol. Chem., 21, 941 (2002), Cunningham, S., et al.: Science, 317, 935 (2007),